Chemistry Unit 1: Matter, Measurement & Math Skills
Quick-reference study sheet
1. Classification of Matter
Separation Techniques
| Technique | Separates | Based On |
|---|---|---|
| Filtration | Solid from liquid (heterogeneous) | Particle size |
| Distillation | Liquids in solution (homogeneous) | Boiling point |
| Chromatography | Dissolved pigments / substances | Polarity / solubility |
| Evaporation | Dissolved solid from liquid | Volatility / boiling point |
| Magnetism | Magnetic solid from mixture | Magnetic properties |
2. Physical vs. Chemical Properties
| Physical Property | Chemical Property |
|---|---|
Observed without changing chemical identity
| Describes ability to become a new substance
|
3. Physical & Chemical Changes; Intensive & Extensive Properties
| Physical Change | Chemical Change |
|---|---|
No new substance; identity preserved; usually reversible
| New substance(s) formed; often irreversible
Signs: gas, precipitate, light/heat, color change, odor |
| Intensive Property | Extensive Property |
|---|---|
Does NOT depend on sample size
Use to identify substances | DOES depend on amount of matter
Change when sample is divided or combined |
4. States of Matter & Phase Changes
Solid
Fixed shape & volume
Tightly packed; vibrate in place; strong forces
Liquid
Fixed volume; takes container shape
Close together; slide past each other; moderate forces
Gas
No fixed shape or volume
Far apart; move rapidly; weak/negligible forces
Phase Changes — absorb energy (endothermic) or release energy (exothermic)
Plasma = 4th state; ionized gas at extremely high temperature (e.g. lightning, stars)
5. SI Units & Metric Prefixes
SI Base Units
| Quantity | Unit | Symbol |
|---|---|---|
| Length | meter | m |
| Mass | kilogram | kg |
| Time | second | s |
| Temperature | kelvin | K |
| Amount of substance | mole | mol |
| Electric current | ampere | A |
| Luminous intensity | candela | cd |
Common Derived Units
| Quantity | Unit / Symbol |
|---|---|
| Volume | L, mL, cm3 |
| Density | g/mL or g/cm3 |
| Speed | m/s |
| Force | N = kg·m/s2 |
| Energy | J = kg·m2/s2 |
| Pressure | Pa = N/m2 |
| Concentration | mol/L (molarity, M) |
Metric Prefixes (memorize kilo through milli at minimum)
| Prefix | Symbol | Power of 10 | Decimal Value |
|---|---|---|---|
| giga | G | 109 | 1,000,000,000 |
| mega | M | 106 | 1,000,000 |
| kilo | k | 103 | 1,000 |
| hecto | h | 102 | 100 |
| deka | da | 101 | 10 |
| (base unit) | — | 100 | 1 |
| deci | d | 10-1 | 0.1 |
| centi | c | 10-2 | 0.01 |
| milli | m | 10-3 | 0.001 |
| micro | μ | 10-6 | 0.000 001 |
| nano | n | 10-9 | 0.000 000 001 |
| pico | p | 10-12 | 0.000 000 000 001 |
6. Accuracy, Precision & Significant Figures
Accuracy vs. Precision
Accuracy: how close a measurement is to the true/accepted value
Precision: how close repeated measurements are to each other (reproducibility)
Precise but inaccurate = consistent results that miss the true value
Accurate but imprecise = correct on average, but scattered
Good measurements are both accurate AND precise
Significant Figure Rules
- All nonzero digits are significant. (456 → 3 sig figs)
- Zeros between nonzero digits are significant. (4006 → 4 sig figs)
- Leading zeros are NOT significant. (0.0023 → 2 sig figs)
- Trailing zeros WITH a decimal point ARE significant. (3.00 → 3 sig figs)
- Trailing zeros WITHOUT decimal are not significant — (100 → 1 sig figs).
Sig Figs in Calculations & Rounding
× and ÷ :
Keep the FEWEST sig figs of all values.
4.56 × 1.4 = 6.384 → 6.4 (2 sig figs)
+ and − :
Keep the LEAST number of decimal places.
12.11 + 18.0 = 30.11 → 30.1 (1 decimal place)
Rounding rule: digit to be dropped ≥ 5 → round up; < 5 → round down (leave as is).
7. Scientific Notation
M × 10n
where 1 ≤ M < 10, and n is a positive or negative integer
Standard → Scientific Notation
- 93,000,000 = 9.3 × 107
(moved decimal 7 places left → n is positive) - 0.000045 = 4.5 × 10-5
(moved decimal 5 places right → n is negative)
Scientific Notation → Standard
- 6.02 × 1023: move decimal 23 places right
- 1.6 × 10-19: move decimal 19 places left
8. Dimensional Analysis (Unit Conversion)
Multiply by conversion factors (fractions equal to 1). Set them up so unwanted units cancel diagonally. Continue until only the desired unit remains.
Example: Convert 5.00 km to cm
- Identify given: 5.00 km; identify target unit: cm
- Set up factors: 5.00 km × 1000 m1 km× 100 cm1 m
- Cancel: km cancels km, m cancels m → cm remains
- Calculate: 5.00 × 1000 × 100 = 5.00 × 105 cm
Common Conversion Factors
9. Density Calculations
Density
d = mV
Mass
m = d × V
Volume
V = md
Units: g/mL (liquids & solutions), g/cm3 (solids), g/L (gases). Note: 1 mL = 1 cm3 exactly.
Example: A sample has mass 52.0 g and volume 20.0 mL. Find density.
- Write formula: d = m / V
- Substitute: d = 52.0 g20.0 mL
- Answer: d = 2.60 g/mL (3 sig figs)
10. Percent Error
% error =|measured − accepted|accepted× 100%
Absolute value bars ensure the result is always positive. Also called percent deviation.
Example: You measured density as 8.90 g/mL; accepted value is 8.96 g/mL.
- Difference: |8.90 − 8.96| = 0.06
- % error = 0.068.96 × 100%
- Answer: 0.67%
Low % error (< 5%)
Close to accepted value → good accuracy. Check procedure for ways to reduce it further.
High % error (> 5%)
Check for systematic error, faulty equipment, parallax, or procedural mistakes.